Redox properties

Recommended data for standard redox potentials and their first and second pressure and temperature derivatives for the alkali and halide half-cell elements considering water as a solvent (book Table 5.25). The reported data includes the redox potential Δ_HV^ɵ (relative to the reference hydrogen electrode), its first and second pressure derivatives ∂_PΔ_HV^ɵ and ∂²_PΔ_HV^ɵ, respectively, its first and second temperature derivatives ∂_TΔ_HV^ɵ and ∂²_TΔ_HV^ɵ, respectively, its cross-second derivative with respect to temperature and pressure ∂²_P,TΔ_HV^ɵ, as well as the metal-solution lateral Volta potential difference Δψ^ɵ_M,S and the real absolute electrode potential V_M,S^ɵ of the alkali and halide half-cell elements. The standard states are corresponding to the bbme_T convention (reference pressure P^ο=1 bar, reference molality b^ο=1 mol·kg^-1 and reference temperature T^-=298.15 K; standard state for the free electron according to the warm-electron convention: ideal-gas at temperature T^-, according to Fermi-Dirac statistics; Fermi-Dirac statistics is also applied for the gas-phase standard state of the proton).